δ18O
Measure of the deviation in the ratio of stable isotopes oxygen-18 and oxygen-16 / From Wikipedia, the free encyclopedia
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In geochemistry, paleoclimatology and paleoceanography δ18O or delta-O-18 is a measure of the deviation in ratio of stable isotopes oxygen-18 (18O) and oxygen-16 (16O). It is commonly used as a measure of the temperature of precipitation, as a measure of groundwater/mineral interactions, and as an indicator of processes that show isotopic fractionation, like methanogenesis. In paleosciences, 18O:16O data from corals, foraminifera and ice cores are used as a proxy for temperature.
It is defined as the deviation in "per mil" (‰, parts per thousand) between a sample and a standard:
- ‰
where the standard has a known isotopic composition, such as Vienna Standard Mean Ocean Water (VSMOW).[1] The fractionation can arise from kinetic, equilibrium, or mass-independent fractionation.